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徐海兵教授

作者:   来源:8858cc永利唯一官方网      发布日期:2021-10-19   浏览:

 

姓名:徐海兵,

职称职务:8858cc永利官网教授、博士生导师。

研究方向主要涉及过渡金属-稀土配合物定向构筑、结构

转换与性能调控研究及产业化应用。

联系电话:15881140373  

邮箱:xhb@hubu.edu.cn

以第一负责人承担国家级项目3项,省部级项目6项,横向及其他项目4项。参与国家自然科学基金重点和科技部973项目4项。在中国科学院福建物构所工作期间获得福建省科学技术二等奖;在中国工程物理研究院工作期间获得中物院科学技术发展基金优秀奖。

Angew. Chem., Nanoscale, Chem. Commun., Chem. Eur. J., Inorg. Chem. Front., Inorg. Chem.等期刊发表SCI论文50余篇。一篇Hot Paper”入选2007年中国稀土十大科技新闻”之第五)一篇Hot Article”、两篇论文被英国皇家化学协会2011年在功能稀土配合物领域评出10篇Top Articles”中排前两位Rare Earth Coordination Chemistry: Fundamentals and Applications发表专著一章。授权国家专利10项。                                                                                         教育背景
2003/09–2006/06,中国科学院福建物质结构研究所,结构化学国家重点实验室,博士
2000/09–2003/06,福州大学,8858cc永利唯一官方网,硕士
1995/09–1999/06,吉林大学,应用化学系,学士
研究工作经历
2017/02  今,8858cc永利官网,8858cc永利唯一官方网,教授

2011/03–2017/01,中国工程物理研究院,化工材料研究所,副研究员,研究员。
2009/01–2011/02,中国科学院福建物质结构研究所,结构化学国家重点实验室, 副研究员
2006/12–2008/12,中山大学与香港大学联合,化学与化学工程学院,博士后
1999/07–2000/08,中国科学经理春应用化学研究所,稀土资源利用国家重点实验室,实验员

部分主持或参与的各类国家、省、市各级项目

  1. 主持项目: 国家自然科学基金-面上项目(NSFC-21571165)《动态可逆结构稀土配合物设计合成及其光谱行为研究》,60万元;起止时间:2016.01-2019.12

  2. 主持项目:中国工程物理研究院×××重大培育专项子课题《用于光纤制备中超纯稀土螯合物xxx制备与表征研究》,117万元;起止时间:2014.08-2015.12

  3. 主持项目: 中国工程物理研究院科学技术发展基金(CAEP2012B0302039)《量子点效应荧光化合物的合成及其硝基炸药传感研究》,18万元;起止时间:2012.07-2014.07

  4. 主持项目: 中国工程物理研究院化工材料研究所创新基金(KJCX-201204)《宽光谱高响应染料设计、制备及其在染料敏化太阳能电池中光电性能研究》,30万元;起止时间:2013.01-2014.12

  5. 主持项目: 福建省青年基金(2011J01065)《异金属稀土化合物的可控合成及其发光性能研究》,7万元;起止时间:2011.01-2013.12

  6. 主持项目: 国家自然科学基金-青年科学基金(NSFC-20901077)《金属配位分子白光发射材料》,22万元;起止时间:2010.01-2012.12

  7. 主持项目: 第41批中国博士后科学基金面上一等资助,(2007-31000-4109337)《有机电致发光新材料技术在显示、照明和背景光中的应用》。 5万元;起止时间:2007.03-2008.12

代表性论文:

  1. Hao Zhuo, Dao-Bin Guan, Jia-Cun He, Hai-Bing Xu*, and Ming-Hua Zeng*. Stepwise increase NdIII-based phosphorescence by AIE-active sensitizer: Broaden AIPE family from transition metals to discrete NIR lanthanide complexes. Chem. Eur. J. 2021, https://doi.org/10.1002/chem.202103028

  2. Menglian Li, Shaorui Li, Kexin Zhang, Xin Chi, Hang Zhou, Hai-Bing Xu,* Yue-Xin Zhang, Quan Li*, Dong Wang, and Ming-Hua Zeng*. Coordination-directed self-assembly of molecular motor: towards a two-wheel drive nanocar. Nanoscale, 2021, 13, 16748-16754.

  3. Jie Wang, Yue Jiang, Jiao-Yang Liu, Hai-Bing Xu,* Yue-Xing Zhang, Xu Peng, Mohamedally Kurmoo, Seik Weng Ng, Ming-Hua Zeng.* Discrete Heteropolynuclear Yb/Er Assemblies: Switching on Molecular Upconversion under Mild Conditions, Angew. Chem. Int. Ed., 2021, 60, 22368-22375.

  4. Hao Zhuo, Xin Chi, Meng-Tian Jiang, Hai-Bing Xu,* and Ming-Hua Zeng*. Switching luminescence of organogold(I) between aggregation-induced phosphorescence enhancement and aggregation-caused quenching by balancing auxiliary ligands around AuI center, Chem. Asian J., 2021, 16, 1165-1170.

  5. Chen Hu, Qing-qing Huang, Hai-Bing Xu,* Yuexing Zhang,a Xu Peng,a and Ming-Hua Zeng*. Concomitant Polymorphs: An Alternative to Modulate Oxygen Evolution Performance of Mononuclear Nickel Complex. Inorg. Chem. Front., 2021, 8, 2486-2491.

  6. Kang-Tai Xiong, Meng-Lian Li, Yue Jiang, Hai-Bing Xu*, and Ming-Hua Zeng*. Imidazole diarylethene switches: an alternative to acid-gated photochromism. New J. Chem., 2020, 44, 8061-8067.

  7. Jun-Quan Zhang, De-Shan Zhang, Qiu-Jie Chen, Hai-Bing Xu,* Mohamedally Kurmoo, MingHua Zeng*, Thermally-induced trans-to-cis isomerization and its photo-induced reversal monitored using absorption and luminescence: Cooperative effect of metal coordination and steric substituent, Chem. Eur. J. 2019, 25, 5177–5185. (Inside Cover)

  8. Yana Liu, Cheng Zhang, Chen Xu, Caixue Lin, Keke Sun, Jie Wang, Xueli Chen, Ling Li*, Andrew K. Whittaker*, and Hai-Bing Xu*, Controlled synthesis of up-conversion luminescent Gd/Tm-MOFs for pH-responsive drug delivery and UCL/MRI dual-modal imaging, Dalton Trans., 2018, 47, 11253-11263.

  9. Hai-Bing Xu,* Jie Wang, Xue-Li Chen, Xu Peng, Kang-Tai Xiong, Dao-Bin Guan, Jian-Guo Deng, Zhi-Hua Deng, Mohamedally Kurmoo, and Ming-Hua Zeng*, Regulating structural dimensionality and emission colors by organic conjugation between SmIII at fixed distance, Dalton Trans., 2018, 47, 6908-6916. (Front Cover)

  10. Hai-Bing Xu*, Xue-Li Chen, Jian-Guo Deng, Zhi-Hua Deng, Shi-Liang Huang, Mohamedally Kurmoo, and Ming-Hua Zeng*, Sensitized near infrared emission through supramolecular d-f energy transfer within an ionic Ru(II) – Er(III) pair, Dalton Trans., 2018, 47, 2073-2078.

  11. Xue-Li Chen#, Hai-Bing Xu#, Xing-Xing Shi, Yuexing Zhang, Tao Yang, Mohamedally Kurmoo, and Ming-Hua Zeng*. Hierarchical Assembly and Aggregation-Induced Enhanced Emission of a Pair of Isostructural Zn14 Clusters, Inorg. Chem., 2017, 56, 14069–14076.

  12. Yan Zhang, Peng-Chong Jiao, Hai-Bing Xu,* Ming-Jing Tang, Xiao-Ping Yang, Shaoming Huang, and Jian-Guo Deng. Switchable sensitizers stepwise lighting up lanthanide emissions, Sci. Rep., 2015, 5, 9335.

  13. Xuefeng Peng, Jian-Guo Deng, and Hai-Bing Xu,* Substituent and solvent effects on the fluorescent and photochromic properties of 2-(2-pyridyl) imidazole containing diarylethene derivatives, RSC Adv., 2013, 3 (46), 24146 - 24153.

  14. Hai-Bing Xu,* Peng-Chong Jiao, Bin Kang, Jian-Guo Deng and Yan Zhang, walkable dual emissions, Sci. Rep. 2013, 3, 2199.

  15. Hai-Bing Xu,* Jian-Guo Deng, Li-Yi Zhang, and Zhong-Ning Chen, Structural and Photophysical Studies on Geometric (Er2Yb2/Yb2Er2) and Configurational (EuTb3/Eu3Tb) Isomers of Heterotetranuclear Lanthanide(III) Complexes, Crys Growth & Des., 2013, 13 (2), 849–857

  16. Hai-Bing Xu*,*Jia Li, Lin-Xi Shi, and Zhong-Ning Chen, “Sensitized luminescence in dinuclear lanthanide(III) complexes of bridging 8-hydroxyquinoline derivatives with different electronic properties” Dalton Trans., 2011, 40, 5549-5556.

  17. Hai-Bing Xu, Jia Li, Li-Yi Zhang, Xin Huang, Zhong-Hui Chen, Bing Li, and Zhong-Ning Chen, “Structures and Photophysical Properties of Homo- and Heteronuclear Lanthanide(III) Complexes with Bridging 2-Methyl-8-Hydroxylquinoline Featuring μ–Phenol Mode” Crys Growth & Des., 2010, 10, 4101-4108.

  18. Hai-Bing Xu,* Ye-Teng Zhong, Wei-Xiong Zhang, Zhong-Ning Chen*, and Xiao-Ming Chen*, “Syntheses, Structures and Photophysical Properties of Heterotrinuclear Zn2Ln Clusters (Ln = Nd, Eu, Tb, Er, Yb)” Dalton Trans., (Hot article) 2010, 39, 5676-5682.

  19. Hai-Bing Xu,* Hui-Min Wen, Zhong-Hui Chen, Jia Li, Lin-Xi Shi, and Zhong-Ning Chen*, “Square Structures and Photophysical Properties of Zn2Ln2 complexes (Ln = Nd, Eu, Sm, Er, Yb)”, Dalton Trans., (Top article) 2010, 39, 1948-1953.

  20. Hai-Bing Xu, Xiao-Ming Chen*, Qi-Sheng Zhang, Li-Yi Zhang, and Zhong-Ning Chen*. “Fluoride-enhanced lanthanide luminescence and white-light emitting in multifunctional Al3Ln2 (Ln = Nd, Eu, Yb) heteropentanuclear complexes”, Chem. Commun., 2009, 7318-7320.

  21. Hai-Bing Xu, Xiao-Ming Chen, Xiu-Ling Li, Li-Yi Zhang, and Zhong-Ning Chen*, “Modulation of Pt→Ln Energy Transfer in PtLn2 (Ln = Nd, Er, Yb) Complexes with 2,2’-Bipyridyl/2,2’:6’2”-Terpyridyl Ethynyl Ligands”, Crys. Growth & Des., 2009, 9, 569-576.

  22. Hai-Bing Xu, Li-Yi Zhang, Lin-Xi Shi, En MaHsiu-Yi Chao, and Zhong-Ning Chen*, “Conformation Changes and Luminescence of AuI-LnIII (Ln = Nd, Eu, Er, Yb) Arrays with 5-Ethynyl-2,2’-Bipyridine”, Inorg. Chem., 2008, 47, 10744-10752.

  23. Hai-Bing Xu, Jun Ni, Kun-Jiao Chen, Li-Yi Zhang, and Zhong-Ning Chen*, “Preparation, Characterization and Photophysical Properties of cis- or trans-PtLn2 (Ln = Nd, Eu, Yb) Arrays with 5-Ethynyl-2,2’-bipyridine”, Organometallics, 2008, 27, 5665-5671.

  24. Hai-Bing Xu, Li-Yi Zhang, Zhong-Hui Chen, Lin-Xi Shi, and Zhong-Ning Chen*, “Sensitization of lanthanide luminescence by two different Pt→Ln energy transfer pathways in PtLn3 heterotetranuclear complexes with 5-ethynyl-2,2’-bipyridine”, Dalton Trans., 2008, 4664-4670.

  25. Hai-Bing Xu, Li-Yi Zhang, Zai-Lai Xie, En Ma, and Zhong-Ning Chen*, “Heterododecanuclear PtII6LnIII6 (Ln = Nd, Gd, Yb) Arrays of 4-Ethynyl-2,2’-Bipyridine with Sensitized Near-Infrared Lanthanide Luminescence by Pt→Ln Energy Transfer”, Chem. Commun., 2007, 2744-2746.

  26. Hai-Bing Xu, Lin-Xi Shi, En Ma, Li-Yi Zhang, Qiao-Hua Wei, and Zhong-Ning Chen*, “PtII Alkynyl Chromophores as Sensitizers for Lanthanide Luminescence in Pt2Ln2 and Pt2Ln4 (Ln = Eu, Nd, Yb) Arrays with Acetylide-functionlized Bipyridine/Phenanthroline”, Chem. Commun., (Hot paper), 2006, 1601-1603.

综述论文:

  1. Hai-Bing Xu,* Ting He, Ming-Jing Tang, Xuefeng Peng, Jian-Guo Deng. progress on photochromic propeties of metal (Ru, Pt, Ln)-diarylethene. Chin. Sci. Bull (Chin Ver), 2014, 59, 2900–2917.

  2. Hai-Bing Xu,* Jian-Guo Deng, and Bin Kang, Designed synthesis and photophysical properties of multifunctional hybrid lanthanide complexes, RSC Adv., 2013, 3 (29), 11367–11384.

专著

1.Zhong-Ning Chen and Hai-Bing Xu, (2010) Near-Infrared (NIR) Luminescence from Lanthanide(III) Complexes, in Rare Earth Coordination Chemistry: Fundamentals and Applications (ed C. Huang), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470824870.ch12 (473-527).

专利:

  1. 徐海兵、邓建国、田勇、黄辉、唐明静。《异四核f-f’同分异构和/或构型异构化合物的制备方法》,专利号ZL-2011-1-0200598.5,申请日:20110718,授权日20140108

  2. 徐海兵、邓建国、康彬、黄辉。《系列聚集诱导移动双重发射光谱的环状稀土配合物及其制备方法》,专利号:ZL-2012-1-0302683.7,申请日:20120823,授权日20150204

  3. 徐海兵、邓建国、康彬、黄辉。《一种浓度、温度传感材料》,专利号:ZL-2013-1-0127970.3,申请日:20130412,授权日20150401

  4. 徐海兵、张衍、焦鹏冲、邓建国、黄辉。《具有集聚诱导荧光增强效应稀土配合物、探针及制备方法》,专利号:ZL-2012-1-0483743.X,申请日:20121123,授权日:2015.08.26

  5. 徐海兵、焦鹏冲、张衍、邓建国。《一类近红外宽光谱金属配合物染料及其制备方法》专利号:ZL-2014-1-0193081.1,申请日:2014.05.08,授权日:2015.12.30

  6. 张衍、邓建国、徐海兵。《大容量全固态氧气发生器》专利号:ZL-2014-1-0407992.X,申请日:2014.08.18,授权日:2016.08.17

  7. 徐海兵、焦鹏冲、张衍、邓建国。《一种双重异稀土荧光探针化合物的制备方法》, 专利号:ZL-2014-1-0455753.1;申请日:2014.09.09,授权日:2016.08.17

  8. 焦鹏冲、徐海兵、何亭、张衍、邓建国。《环金属配体染料,染料敏化电极和太阳能电池》专利号:ZL-2014-1-0436437.X; 申请日:2014.08.29,授权日:2017.06.06

  9. 徐海兵、焦鹏冲、唐明静、陈莹、杜云巍、邓建国、蒋道建等《纯化高稳定易挥发性金属螯合物的方法》,专利号:ZL-2015-1-0183819.0; 申请日:2015.04.17, 授权日:2017.10.20.

  10. 焦鹏冲,徐海兵,邓建国,《一种稀土氧化物分离纯化的前处理方法》,专利号:ZL-2016-1-0082065.4, 申请日:20160205,授权日:20180501

  11. 徐海兵,《一种低成本超高纯易挥发稀土螯合物的制备方法》,申请专利号:201911203722.6, 申请日:20191129.

  12. 徐海兵,《超高纯光纤预制棒稀土掺杂试剂的低成本改良制备方法》,申请专利号:201911201714.8,申请日:20191129.  

  13. 黄青青徐海兵,《一种高稳定、易挥发、超高纯异核稀土螯合物的制备方法》,申请专利号:2021107407790,申请日:20210701.

可转化项目:

1)超高纯稀土螯合物:

  应用瓶颈:光纤激光技术研究包括关键材料、核心器件以及系统与装备。就关键材料而言,石英光纤(芯棒)决定了光纤的性能,高纯度、高稳定性,易挥发稀土螯合物试剂是采用OVD制备高功率激光光纤预制棒的关键材料,目前都是从国外进口获得。

  我们开辟了梯度气相法纯化制备公斤级超高纯稀土螯合物,其整体指标不低于进口样品,部分优于进口指标。由陕西瑞海丽君环境科技有限公司代理,武汉安扬激光技术有限责任公司、西安光学精密机械研究所以及中国工程物理研究院与我们陆续订货。

 

 


 

 

产品指标及进展如下:

获得稳定的超高纯稀土螯合物Ln(TMHD)3 (Ln = Yb, Nd, Er, Tm, Ce)的设计合成及纯化工艺;其中稀土相对纯度≥6 N;在稀土元素和上述干扰金属杂质元素中纯度≥5.5 N

主要干扰金属杂质Fe, Cu, 含量低于200 ppb;Cr, Mn, Co, Ni, V 等含量低于50 ppb;

通过结构调整,将La,Ce螯合物的升华温度降低到200 ℃以下;

通过异核稀土螯合物实现多物种不同浓度一步掺杂,精简高性能光纤预制棒的制备工艺和流程。

 

2)便携式氧烛:

该成果可解决的问题:无电、无高压、密闭空间供氧;

创新点:含氧量高,产品体积小(体积是压缩氧体积的1/3);寿命长,无需外加动力消耗;安全可靠,无高压泄露爆燃、爆炸的危险;供氧温度低,无呼吸阻力,呼吸舒适。

应用场景:密闭空间,应急防备,单兵或个人固体供氧装置。

主要技术指标:

① 氧气(99.5% 最低);二氧化碳(不超过1000 ppm);一氧化碳(不超过25 ppm);其它(甲烷、氮氧化物等)(不超过 1 ppm);;

② 重量<2公斤,供氧时间30、45以及60分钟,供氧速率2-4L/mins,供氧温度<40℃;或15公斤供氧3000L,供氧时间60分钟;贮存寿命:>5年

 

 

 

 

 

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